Ceria-Based Mixed Metal Oxides Assist in Clean Hydrogen Oxidation

Characterization of SO2-Poisoned Ceria-Zirconia Mixed Oxides

CeO2, ZrO2, and a series of CexZr1-xO2 catalysts with 1 wt% Pd were exposed to fixed exposures of SO2 under oxidizing environments and then characterized by FTIR, pulse-reactor studies with CO and O2, and temperature-programmed desorption (TPD). For exposures above 473 K, sulfates were formed on all of the materials; however, the results are consistent with the formation of bulk sulfates on CeO...

Design of Nanosized Ceria-zirconia Mixed Oxides for Catalytic Applications

Heterogeneous Partial (amm)Oxidation and Oxidative Dehydrogenation Catalysis on Mixed Metal Oxides

This paper presents an overview of heterogeneous partial (amm)oxidation and oxidative dehydrogenation (ODH) of hydrocarbons. The review has been voluntarily restricted to metal oxide-type catalysts, as the partial oxidation field is very broad and the number of catalysts is quite high. The main factors of solid catalysts for such reactions, designated by Grasselli as the “seven pillars”, and pl...

Phase Transition in Mixed Transition Metal Oxides under High Pressure

Mixed crystals can be categorized as the crystal in which two or more different types of atoms are present and configured. These atoms interact each other in the influence of Coulomb force of attraction and the presence of short range repulsion force. Due to this interaction they tends to be arranged in equilibrium state and forms new material. A pure crystal can be doped by impurities with pro...

Sustainable selective oxidations using ceria-based materials

This Perspective covers sustainable oxidation processes using doped cerias, ceria-supported catalysts and ceria-based mixed oxides. Firstly, we consider the general properties of ceria-based catalysts. We outline the advantages of the ceria redox cycle, and explain the dynamic behaviour of these catalysts in the presence of metal additives and dopants. We then review three types of catalytic ox...