catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butylisophthalato]
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چکیده
منابع مشابه
catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butylisophthalato]
In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl-isophthalate (tbip) and one 2,2'-bipyridine (bpy) ligand. The copper(II) ion is four-coordin-ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts...
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The title compound, [Sn(C4H9)2(C2O4)] n , an unexpected side product in the reaction of di-tert-butyl-tin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn(IV) atom of the one-dimensional coordination polymer is located on a mirror plane and is coordinated by two chelating oxalate ions with two rather different Sn-O bond lengths of...
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The title compound, [Ni(C(8)H(3)BrO(4))(C(5)H(5)N)(3)], is the first structurally characterized complex with a transition metal coordinated by a 5-bromo-isophthalate anion. The Ni(II) ion is coordinated by three O atoms from the carboxyl-ate groups and three N atoms from three pyridine ligands in a distorted octa-hedral coordination geometry. The 5-bromo-isophthalate anion is planar within 0.05...
متن کاملcatena-Poly[[dipyridinecadmium(II)]-μ-5-amino-2,4,6-triiodoisophthalato]
The hydro-thermal reaction of cadmium(II) nitrate with 5-amino-2,4,6-triiodo-isophthalic acid and pyridine in DMF solution leads to the formation of the title compound, [Cd(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra-hedral geometry, which lies on a crystallographic twofold rotation axis. The Cd(2+ )ion is bonded to two N atoms ...
متن کاملcatena-Poly[[aqua(2,2′-bipyridyl)cobalt(II)]-μ-5-nitroisophthalato]
In the crystal structure of the title compound, [Co(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers, which are approximately related by noncrystallographic inversion symmetry. Each zigzag chain is constructed from one Co(II) ion, one O-monodentate 5-nitro-isophthalate (ndc) dianion, one N,N'-bidentate 2,2'-bipyridyl ligand and o...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808035484