Catalytic Transfer of Magnetism Using a Neutral Iridium Phenoxide Complex
نویسندگان
چکیده
منابع مشابه
An electron poor iridium pincer complex for catalytic alkane dehydrogenation.
A novel electron deficient 4,6-bis(trifluoromethyl)-1,3-phenylene diphosphinite ligand 4 was developed and synthesized. Reaction of Ir precursors with ligand 4 gave chloro(hydride) pincer complex 5, which demonstrated a higher TON in alkane dehydrogenation reactions compared to similar phosphinite based pre-catalysts. The formation of cyclooctene (COE) and tert-butylethylene adducts of the 14e ...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2015
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.5b00311