Catalytic Applications of Large Pore Sulfonic Acid-Functionalized SBA-15 Mesoporous Silica for Esterification
نویسندگان
چکیده
منابع مشابه
Synthesis and characterization of large-pore vinyl-functionalized mesoporous silica SBA-15.
Ordered mesoporous silicas SBA-15 with high loadings of pendant vinyl groups have been synthesized via co-condensation of tetraethoxysilane (TEOS) and triethoxyvinylsilane (TEVS) templated with a triblock copolymer.
متن کاملPore-expanded SBA-15 sulfonic acid silicas for biodiesel synthesis.
Here we present the first application of pore-expanded SBA-15 in heterogeneous catalysis. Pore expansion over the range 6-14 nm confers a striking activity enhancement towards fatty acid methyl ester (FAME) synthesis from triglycerides (TAG), and free fatty acid (FFA), attributed to improved mass transport and acid site accessibility.
متن کاملSelective Preparation of Furfural from Xylose over Sulfonic Acid Functionalized Mesoporous Sba-15 Materials
Sulfonic acid functionalized mesoporous SBA-15 materials were prepared using the co-condensation and grafting methods, respectively, and their catalytic performance in the dehydration of xylose to furfural was examined. SBA-15-SO3H(C) prepared by the co-condensation method showed 92–95% xylose conversion and 74% furfural selectivity, and 68–70% furfural yield under the given reaction conditions...
متن کاملEfficient enrichment of glycopeptides with sulfonic acid-functionalized mesoporous silica.
This work presents an efficient and selective enrichment method for glycoprotein/glycopeptides with sulfonic acid-functionalized mesoporous silica (SBA-15-SO3H), which is synthesized via simple oxidation of -SH groups with H2O2. The functionalized SBA-15 shows large surface area and accessible pores, and can selectively adsorb glycopeptides via hydrogen bond and hydrophilic interaction. Upon th...
متن کاملAcid-Functionalized SBA-15-Type Silica Catalysts for Carbohydrate Dehydration
Acid-Functionalized SBA-15-Type Silica Catalysts for Carbohydrate Dehydration Anthony J. Crisci, Mark H. Tucker, Ming-Yung Lee, Se Gyu Jang, James A. Dumesic,* and Susannah L. Scott* Department of Chemistry & Biochemistry, Department of Chemical Engineering, and Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States Department of Chemical Enginee...
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ژورنال
عنوان ژورنال: Open Chemistry
سال: 2018
ISSN: 2391-5420
DOI: 10.1515/chem-2018-0132