Carbon Fabric Reinforced Addition-Cure Phenolic Resins Based on Propargyl and Allyl Ether Functional Novolac Produced

Characterization of Phenolic Resins and Their Co-Cure with Other Matrix Resins

Poly(allyl glycidyl ether)-A versatile and functional polyether platform.

Allyl glycidyl ether, polymerized from potassium alkoxide/naphthalenide initiators under both neat and solution conditions was shown to be a highly-controlled process. In both cases, molar masses (10-100 kg/mol) were determined by the reaction stoichiometry, and low polydispersity indices (1.05-1.33) could be obtained with a full understanding of the dominant side reaction, isomerization of the...

Carbon Nanofiber Reinforced Carbon/Polymer Composite

Conventional carbon fiber reinforced phenolic resins are widely used to prepare carbon/carbon composites due to their high carbon yield. Property enhancement of carbon fabric/phenolic composites is possible through carbon nanomaterial dispersion in the matrix. The effect of carbon nanofiber dispersion in phenolic resins/carbon fabric composites was investigated. The dispersion efficiency in dif...

Rhenium-catalyzed coupling of propargyl alcohols and allyl silanes.

A mild method for the regioselective coupling of propargyl alcohols and allylsilanes is described. The method employs an air- and moisture-tolerant rhenium-oxo complex ((dppm)ReOCl3) as a catalyst for the formation of sp3-carbon-sp3-carbon bonds without the need for prior activation of the propargyl alcohol as a halide or pseudohalide. The stability of the high oxidation state rhenium complex a...

Quantum mechanistic insights on aryl propargyl ether Claisen rearrangement.

The mechanism of aryl propargyl ether Claisen rearrangement in gas and solvent phase was investigated using DFT methods. Solvent phase calculations are carried out using N,N-diethylaniline as a solvent in the PCM model. The most favorable pathways involve a [3,3]-sigmatropic reaction followed by proton transfer in the first two steps and then deprotonation or [1,5]-sigmatropic reaction. Finally...