منابع مشابه
Bromination of Alkenes
The two most common halogenation reactions are chlorination and bromination. The addition of these halogens to alkenes yields 1,2-dihalides. Chlorinations reactions are used to synthesize over 6 million tons per year of ethylene dichloride (1,2-dichloroethane) for use as a solvent and for subsequent polymerization to produce poly(vinylchloride) known more commonly as PVC which is used for plumb...
متن کاملSelective Mono Bromination of 1,4-Dihydropyridines
2-monobromomethyl 1,4-dihydropyridines is selectively synthesized by bromination of the parent compound by 1.1 equivalents of pyridinium bromide perbromide in dichloromethane/pyridine at -20 °C. The same reagent in dichloromethane at 0 °C produce the 2,6-bis(bromomethyl) 1,4-dihydropyridines.
متن کاملBromination of Ketones by Palladium(II). An Asymmetric α-Bromoketones Catalytically Synthesized by a Mono Palladium(II) Catalyst
The oxidation of ketones by monometallic [Pd(CH3CN)2(S)-Tol-BINAP](BF4)2 A or [Pd(CH3CN)2(S)-METBOX](BF4)2 B in aqueous THF containing copper(II) bromide produced chiral α-bromoketones. The α-bromoketone products were obtained with moderate to high enantiomeric excess (68-89% ee) and good isolated yields (70-90%). The highest optical purities were 89% ee for cycloheptanone. Catalyst B gave slig...
متن کاملUnexpected bromination ring-opening of tetraarylporphyrins.
An unexpected, mild, efficient bromination ring-opening method has been developed for convenient synthesis of various novel biladienes or brominated porphyrins by controlling the amounts of NBS used.
متن کاملRegioselective bromination of fused heterocyclic N-oxides.
A mild method for the regioselective C2-bromination of fused azine N-oxides is presented, employing tosic anhydride as the activator and tetra-n-butylammonium bromide as the nucleophilic bromide source. The C2-brominated compounds are produced in moderate to excellent yields and with excellent regioselectivity in most cases. The potential extension of this method to other halogens, effecting C2...
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1950
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.71.435