Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
نویسندگان
چکیده
منابع مشابه
4-Amino-3-ammoniopyridinium dinitrate
In the crystal structure of the title compound, C(5)H(9)N(3) (2+)·2NO(3) (-), the cations and anions are connected by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by π⋯π inter-actions between pyridinium rings [centroid-centroid distance = 3.775 (4) Å].
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The stereoselectivity in the reduction of 4-benzoylpyridine (4-BP) was examined in the cytosolic fractions from the heart of 9 vertebrates (pig, rabbit, guinea pig, rat, mouse, chicken, soft-shelled turtle, frog and flounder). 4-BP was stereoselectively reduced to S(-)-alpha-phenyl-4-pyridylmethanol [S(-)-PPOL] in the cytosolic fractions from the heart of pig, rabbit and guinea pig. However, of...
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In the crystal structure of the title salt, C9H22N2 (2+)·2NO3 (-), the piperidine ring of the dication adopts a chair conformation and the orientation of the C-NH3 bond is equatorial. The ions are linked by normal and bifurcated N-H⋯O hydrogen bonds in R 2 (2)(6), two R 4 (2)(8) and R 3 (4)(14) graf-set motifs, generating a three-dimensional network.
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Três complexos inéditos do tipo [Cu(HL)Cl 2 ] foram obtidos com N(4)-orto (H2Bz4oT, HL1), N(4)-meta (H2Bz4mT, HL2) e N(4)-para-toluil-2-benzoilpiridina tiossemicarbazona (H2Bz4pT, HL3), nos quais a tiossemicarbazona coordena-se ao metal por meio do sistema quelante N py N-S. H2Bz4pT (HL3) cristaliza-se no grupo espacial P1 – , a = 9,509(3) Å, b = 9,807(4) Å, c = 11,564(4) Å; α = 100,76(2)°, β =...
متن کاملBis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
In the title complex, [Cu(C(13)H(11)N(3)O(2))(2)(C(12)H(8)N(2))](NO(3))(2), the Cu(II )atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the Cu(II)atom by a pyridine N atom. These four atoms form a slightly distorted square-planar N(4) donor set. In the packing, two additional Cu⋯O inte...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810038985