Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI)
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چکیده
منابع مشابه
Bis[bis(1,10-phenanthroline-κ2 N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI)
The title compound, [Cu(C(12)H(8)N(2))(2)](2)[W(6)O(19)], consists of two [Cu(phen)(2)](+) cations (phen = 1,10-phenanthroline) and one typical [W(6)O(19)](2-) isopolyanion. The Cu(I) atom is coordinated by four N atoms from two bidentate chelating phen ligands in a distorted tetra-hedral geometry. The hexa-tungstate anion, lying on an inversion center and possessing the well known Lindqvist st...
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In the title compound, (C(5)H(7)N(2))(6)[V(10)O(28)]·2H(2)O, the [V(10)O(28)](6-) anion is generated by crystallographic inversion symmetry and each of the five vanadium centres adopts a distorted VO(6) octa-hedral geometry. In the crystal structure, a network of N-H⋯O, N-H⋯(O,O) and O-H⋯O hydrogen bonds helps to establish the packing.
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In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6-) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa-hedral geometry. Eight terminal O atoms are bonded to V(V) atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network ...
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In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the aryl-imido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N-C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group, and is typical for the imido monodentate behaviour described in analogous hybrids. Light componen...
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In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa-hedral geometry. The [W(6)O(19)](2-) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809020170