Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ2O4,O5]bis(1,10-phenanthroline-κ2N,N′)dysprosium(III) dihydrate
نویسندگان
چکیده
منابع مشابه
(6-Oxido-2-oxo-1,2-dihydropyrimidine-5-carboxylato-κ2 O 5,O 6)(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ2 O 4,O 5)bis(1,10-phenanthroline-κ2 N,N′)erbium(III) dihydrate
The erbium(III) atom in the title compound, [Er(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(C(12)H(8)N(2))(2)]·2H(2)O, is located on a twofold rotation axis and chelated by two 1,10-phenanthroline heterocycles as well as by a 2,4-dihydroxy-pyrimidine-5-car-box-yl-ate monoanion and a 2,4-dihydroxy-pyrimidine-5-car-box-yl-ate dianion in a square-anti-prismatic coordination geometry.
متن کاملBis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ2 O 4,O 5]bis(1,10-phenanthroline-κ2 N,N′)dysprosium(III) dihydrate
In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-anti-prismatic geometry by two chelating 1,10-phenanthroline mol-ecules as well as two 4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-) anions. N-H⋯O and O-H⋯O hydrogen bonds help to stabilize the crystal structure. The ...
متن کامل(4-Oxido-2-oxo-1,2-dihydropyrimidine-5-carboxylato-κ2 O 4,O 5)(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ2 O 4,O 5)bis(1,10-phenanthroline-κ2 N,N′)gadolinium(III) dihydrate
The title compound, [Gd(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(C(12)H(8)N(2))(2)]·2H(2)O, was obtained from a solvothermal reaction of 2,4-dihydroxy-pyrimidine-5-carboxylic acid (H(3)iso), GdCl(3)·6H(2)O and 1,10-phenanthroline (phen). The Gd(III) ion is located on a twofold rotation axis and is coordinated by four N atoms from two chelating phen ligands and four O atoms (5-carboxyl-ate and 4-oxid...
متن کامل2,6-Diamino-4-oxo-3,4-dihydropyrimidin-1-ium chloride dihydrate
In the crystal structure of the title compound, C(4)H(7)N(4)O(+)·Cl(-)·2H(2)O, adjacent cations are connected to one another through N-H⋯O hydrogen bonds, forming infinite chains along the b axis. These chains are further hydrogen bonded to the chloride anions and water mol-ecules, resulting in a three-dimensional network. The pyrimidine rings of adjacent mol-ecules are arranged in an anti-para...
متن کاملHexaaquamagnesium 5-[1-(carboxylatomethyl)pyridin-1-ium-4-yl]tetrazol-2-ide chloride dihydrate
In the title compound, [Mg(H(2)O)(6)](C(8)H(6)N(5)O(2))Cl·2H(2)O, the Mg(II) ion is surrounded by six water mol-ecules, exhibiting a slightly distorted octa-hedral coordination. The pyridine and tetra-zole rings are nearly coplanar, forming a dihedral angle of 4.63 (3)°. The complex cations, zwitterionic organic anions, Cl(-) anions and uncoordinated water mol-ecules are connected by O-H⋯O, O-H...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809036848