Binder driven self-assembly of metal-organic cubes towards functional hydrogels
نویسندگان
چکیده
منابع مشابه
Directional self-assembly of a colloidal metal-organic framework.
Materials science is at an early stage of learning to employ anisotropic interaction in self-assembly. One important approach towards this goal involves the study of nm-sized particles, but we note two limitations: first that this is a rather special case as the range of inter-particle interaction in suspensions is typically likewise nm in size, and secondly that the diffraction limit precludes...
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The combination of an amide containing a linear ligand (L1) and an organometallic molecular "clip" (clip-1) leads to the self-assembly of a Pt4 nanoscopic framework representing the first example of a Pt-based molecular rectangle (rectangle-1) incorporating amide functionality. A complementary approach was also followed to prepare a Pd(II)-based molecular rectangle (rectangle-2) by reaction of ...
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Herein we disclose the development of two complementary single stranded DNA-small molecule chimeras (DCs) that by themselves only bind weakly to a protein target (human serum albumin; HSA). However, upon self-assembly, the DC duplex facilitates a ligand migration reaction leading to a covalently fastened high-affinity, bidentate, protein-binder that resides at the terminus of only one of the DC...
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The anisotropy of attractive interactions between particles can favor, through a self-assembly process, the formation of linear semi-flexible chains. In the appropriate temperatures and concentration ranges, the growing aspect ratio of the aggregates can induce formation of a nematic phase, as recently experimentally observed in several biologically relevant systems. We present here a numerical...
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ژورنال
عنوان ژورنال: Nature Communications
سال: 2018
ISSN: 2041-1723
DOI: 10.1038/s41467-018-05818-w