Atomization Mechanisms of Gold Dispersed on Pyrolytic Graphite Surface in Graphite Furnace Atomic Absorption Spectrometry
نویسندگان
چکیده
منابع مشابه
GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY WITH MAlIlRIX MODIFICATION FOR DETERMINATION OF LEAD IN DRINKING WATER
An amoniumvanadate plus sodium molybdate mixed modifier Graphite Furnace Atomic Absorption Spectrometric method has been developed for determination of traces of lead in drinking water. The concentration of lead in the sample is obtained by direct comparison to linear working graph prepared from aqueous standards in the modifier medium, The results indicate the better performance of the pro...
متن کاملUtilization of electrodeposition on a graphite probe modified with palladium in determination of lead by graphite furnace atomic absorption spectrometry in water and environmental samples
In this work a rapid and selective procedure for separation and preconcentration of lead(Pb2+) before determination by electrothermal atomic absorption spectrometry (ETAAS) wasdeveloped. The procedure is based on the electrodeposition on a graphite probe modified withpalladium. The lead was deposited from acetate buffer solution at pH 5.5. Various parameters,such as pH of solutions, deposition ...
متن کاملEffect of the chemical species of arsenic on sensitivity in graphite furnace atomic absorption spectrometry.
The sensitivity of graphite furnace atomic absorption spectrometry (GFAAS) to arsenobetaine (AB) was 1.3-times higher than to inorganic As. In order to understand the mechanism underlying this observation, the atomization processes for both chemical species were investigated in terms of the enthalpy change (DeltaH) during the atomization process in GFAAS. The enthalpy change of AB was slightly ...
متن کاملgraphite furnace atomic absorption spectrometry with malilrix modification for determination of lead in drinking water
an amoniumvanadate plus sodium molybdate mixed modifier graphite furnace atomic absorption spectrometric method has been developed for determination of traces of lead in drinking water. the concentration of lead in the sample is obtained by direct comparison to linear working graph prepared from aqueous standards in the modifier medium, the results indicate the better performance of the propose...
متن کاملDirect Determination of Tin in Human Hair by Graphite Furnace Atomic Absorption Spectrometry Using Air Ashing in Graphite Tube
Direct determination of tin in human hair was performed by graphite furnace atomic absorption spectrometry. Human hair was cut into 3-5 mm long and 1-2 mg of the sample was directly introduced into a pyrolytically coated graphite tube, of which the injection hole was enlarged to a diameter of approximately 5 mm. After introduction of the sample, 20 μl of 30 mg Pd/l in 1 mol/l HCl was added as a...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 2008
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.57.677