Atomic Mechanisms of Crystallization in Nano-Sized Metallic Glasses
نویسندگان
چکیده
Understanding crystallization mechanisms in nano-sized metallic glasses (MGs) is important to the manufacturing and application of these new nanomaterials that possess a unique combination structural functional properties. Due two-dimensional projections limited spatial and/or temporal resolutions experiments, significant questions (e.g., whether nucleation takes place on free surface or near-surface layer) regarding this subject remain under debate. Here, we address outstanding using molecular dynamics simulations MG nanorods together with atomistic visualization data analysis. We show MGs predominantly by converting high-energy liquid lower-energy crystal (the most close-packed atomic plane). This true for all different diameters studied. On other hand, apparent growth mode (inward/radial, lateral longitudinal) resulting grain structure are more dependent nanorod diameter. For relatively big diameter nanorod, overall rate does not differ much among three directions grains approximately semispherical. small diameters, appear grow longitudinal direction some may form long single-crystal segments along length nanorod. The reasons difference discussed. study provides direct insights into MGs, which can facilitate advanced materials.
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ژورنال
عنوان ژورنال: Crystals
سال: 2022
ISSN: ['2073-4352']
DOI: https://doi.org/10.3390/cryst13010032