AT-CuAAC Synthesis of Mechanically Interlocked Oligonucleotides
نویسندگان
چکیده
منابع مشابه
A mechanically interlocked bundle.
The prototype of an artificial molecular machine consisting of a trisammonium tricationic component interlocked with a tris(crown ether) component to form a molecular bundle with averaged C(3v) symmetry has been designed and synthesized. The system is based on noncovalent interactions, which include 1) N(+)-H...O hydrogen bonds; 2) C-H...O interactions between the CH(2)NH(2) (+)CH(2) protons on...
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This tutorial review describes the evolution of the field of chemical templation, in particular, emphasising the impact its application has made to the synthesis of mechanically interlocked structures. Recent advances in the use of negatively charged template species for the synthesis of interlocked structures are detailed, with the main focus of this review describing the development of a gene...
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Recent investigations on the design and synthesis of electrochromic materials based on switchable three-station [2]catenanes are summarized. The reasoning and preliminary experiments behind the design of electrochemically controllable red-green-blue (RGB), donor-acceptor [2]catenanes are presented. A basis for color generation is discussed in which the tetracationic cyclophane, cyclobis(paraqua...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2020
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.0c01670