Aromatic Rearrangements
نویسندگان
چکیده
منابع مشابه
Subtelomeric Rearrangements in Patients with Recurrent Miscarriage
Objective The Subtelomeric rearrangements are increasingly being investigated in cases of idiopathic intellectual disabilities (ID) and congenital abnormalities (CA) but have also been suspected to be responsible for unexplained recurrent miscarriage (RM). We have noticed a higher risk of subtelomeric translocations in association with CA and ID. Such rearrangements can go unnoticed through con...
متن کاملAromatic Iodides from Aromatic Organomercurials 13.2. Aromatic Bromides from Aromatic Organomercurials 13.3. Aromatic Chlorides from Aromatic Organomercurials 13.4. Aromatic Fluorides from Aromatic Organomercurials 13.5. Aromatic Nitriles from Aromatic Organomercurials 14. Improved Syntheses of Some Diaryliodonium Salts from Symmetric Diarylmercurials
This review reports some novel (or improved) synthetic methods for preparing a number of aromatic (carbocyclic and predominantly heterocyclic) organomercurials, particularly those derived from theophylline, theobromine and uracil, as well as some novel haloand cyano-demercuration reactions. We have also synthesized the first stable organic derivative of mercury(I), viz. 1,8-bis(acetoxydimercuri...
متن کاملConvex Rearrangements
For a process X(t), t ≥ 0 with stationary increments, observed at Let, further Y 0:N ≤ Y 1:N ≤ · · · ≤ Y (N −1):N denote the order statistic of Y 's from (1). A convex rearrangement of X(t) is defined as VX N (t) = X(0) + [N t]−1 i=0 Y i:N + (N t − N t)Y N t:N , 1 is stationary with variance σ 2 N = EY 2 1,N and covariance γ N (h) = EY k,N Y k+h,N. investigated the asymptotic behavior of normal...
متن کاملAromatic-aromatic Interactions in Protein/peptide Folding
While, intramolecular hydrogen bonds have attracted the greatest attention in studies of peptide conformations, the recognition that several other weakly polar interactions may be important determinants of folded structure has been growing. Burley and Petsko provided a comprehensive overview of the importance of weakly polar interactions, in shaping protein structures. The interactions between ...
متن کاملCaryolene-forming carbocation rearrangements
Density functional theory calculations on mechanisms of the formation of caryolene, a putative biosynthetic precursor to caryol-1(11)-en-10-ol, reveal two mechanisms for caryolene formation: one involves a base-catalyzed deprotonation/reprotonation sequence and tertiary carbocation minimum, whereas the other (with a higher energy barrier) involves intramolecular proton transfer and the generati...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1965
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.23.713