Aquabis(3,5-dimethyl-1H-pyrazole-κN2)(oxydiacetato-κ3O,O′,O′′)copper(II) dihydrate
نویسندگان
چکیده
منابع مشابه
Aquabis(3,5-dimethyl-1H-pyrazole-κN 2)(oxydiacetato-κ3 O,O′,O′′)copper(II) dihydrate
In the title compound, [Cu(C(4)H(4)O(5))(C(5)H(8)N(2))(2)(H(2)O)]·2H(2)O, the Cu(II) cation assumes a distorted octa-hedral coordination geometry formed by two 3,5-dimethyl-1H-pyrazole ligands, one oxydiacetate (ODA) dianion and one coordinated water mol-ecule. The tridentate ODA ligand chelates to the Cu cation in a facial configuration with a longer Cu-O bond [2.597 (3) Å], and both chelating...
متن کامل5-Chloromethyl-1,3-dimethyl-1H-pyrazole
The pyazole ring in the title compound, C(6)H(9)ClN(2), is almost planar (r.m.s. deviation = 0.003 Å). In the crystal, mol-ecules are linked by C-H⋯N inter-actions, forming [100] chains.
متن کاملDimethyl 1-cyanomethyl-1H-pyrazole-3,5-dicarboxylate
The title mol-ecule, C(9)H(9)N(3)O(4), syhthesized from 1H-pyrazole-3,5-dicarboxylic acid and 2-bromo-acetonitrile, is approximately planar; the inter-planar angles between the pyrazole ring and the mean planes of the two carboxylate units and the cyanomethyl unit are 4.49 (10), 5.56 (9) and 5.03 (19)°, respectively. In the crystal, inversion dimers linked by pairs of weak C-H ⋯O bonds occur, a...
متن کامل3,5-Dimethyl-4-nitroso-1H-pyrazole
In the unit cell of the title compound, C(5)H(7)N(3)O, there are two conformers (A and B) which differ in the position of the oxime group with respect to the protonated pyrazole nitro-gen (trans in the A conformer and cis in the B conformer) and in the geometric parameters. The oxime group exists in the nitroso form in both conformers. In the crystal, mol-ecules are linked by inter-molecular N-...
متن کامل3,5-Dimethyl-1-(4-nitrophenyl)-1H-pyrazole
In the title pyrazole derivative, C(11)H(11)N(3)O(2), the benzene ring is twisted [dihedral angle = 31.38 (12)°] with respect to the pyrazole ring (r.m.s. deviation = 0.009 Å). The nitro group is effectively coplanar with the benzene ring to which it is attached [O-N-C-C torsion angle = -6.5 (3)°]. Supra-molecular chains along the b axis are formed owing to π-π inter-actions [3.8653 (2) Å] betw...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811015169