Anion Exchange Doping: Tuning Equilibrium to Increase Doping Efficiency in Semiconducting Polymers
نویسندگان
چکیده
High electron affinity (EA) molecules p-type dope low ionization energy (IE) polymers, resulting in an equilibrium doping level based on the energetic driving force (IE-EA), reorganization energy, and dopant concentration. Anion exchange (AED) is a process whereby anion exchanged with stable ion from electrolyte. We show that AED can be predicted using isotherm model. The of (FeCl3-) for bis(trifluoromethanesulfonamide) (TFSI-) polymers poly(3-hexylthiophene-2,5-diyl) (P3HT) poly[3-(2,2-bithien-5-yl)-2,5-bis(2-hexyldecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione-6,5-diyl] (PDPP-2T) highlights two cases which nonspontaneous spontaneous, respectively. For P3HT, FeCl3 provides high but unstable counterion, so results air counterion marginal increase doping. PDPP-2T, weak dopant, FeCl3- TFSI- increases by >10× AED.
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ژورنال
عنوان ژورنال: Journal of Physical Chemistry Letters
سال: 2021
ISSN: ['1948-7185']
DOI: https://doi.org/10.1021/acs.jpclett.0c03620