Aniline hydrogenolysis on nickel: effects of surface hydrogen and surface structure
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چکیده
منابع مشابه
Aniline hydrogenolysis on nickel: effects of surface hydrogen and surface structure
Fluorescence yield near-edge spectroscopy (FYNES) above the carbon K edge and temperature programmed reaction spectroscopy (TPRS) have been used as the methods for characterizing the reactivity and structure of adsorbed aniline and aniline derived species on the Ni(100) and Ni(111) surfaces over an extended range of temperatures and hydrogen pressures. The Ni(100) surface shows appreciably high...
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Single crystal catalysts have been used to investigate ethane hydrogenolysis. The apparatus used in these studies allows for catalyst preparation and surface characterization in ultrahigh vacuum (UHV) with an in vacua transfer to a second UHV chamber designed for high pressure kinetic studies. Kinetic measurements on single crystals of nickel show the hydrogenolysis of ethane to be “structure s...
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The adsorption of hydrogen on a clean Ni(100) single crystal surface was studied in UHV between 120 K and 500 K means of LEED, thermal desorption spectroscopy and work function measurements. H2 chemisorption occurs in two atomic states ßi and ßz with maximum desorption rates (at saturation) at 318 K and 348 K. The activation energy for desorption was determined to be 20 ( ± 2) kcal/mole for the...
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ژورنال
عنوان ژورنال: Catalysis Letters
سال: 1995
ISSN: 1011-372X,1572-879X
DOI: 10.1007/bf00806886