Analysis of sintering behavior of silicon nitride based on master sintering curve theory of liquid phase sintering

Low Temperature Sintering Additives for Silicon Nitride

This work deals with sintering additives for the low temperature pressureless sintering of Si3N4, via a transient liquid technique. Much attention has been given to the development of a sintering process using low-cost Si3N4 powder (Silzot HQ, Germany) as the starting material and employing sintering additives which are also both economically attractive and enable sintering at low temperatures....

An Update on the Theory of Supersolidus Liquid Phase Sintering

Prealloyed powders usually melt over a range of temperatures. This feature is useful in performing supersolidus liquid phase sintering, where liquid forms inside the particles when heated just over the solidus temperature. Densification by supersolidus liquid phase sintering is sensitive to time-temperatures. A major difficulty arises when a narrow temperature range exists between densification...

Solid Solution Formation during Liquid Phase Sintering

Master sintering curve for Gd-doped CeO2 solid electrolytes

The sintering behavior of gadolinia-doped ceria powders was studied by the master sintering curve (MSC). Dilatometric analyses of powders produced by a soft chemical method were performed to provide the experimental data set for the construction of the MSC. The assumed model provided good fittings of the MSC and the activation energy for the sintering of Ce1-xGdxO3-d, with x = 0, 0.05, 0.1, and...

Evaluation of Heterogeneous Densification, Anisotropic Shrinkage and Rheological Behavior of Ceramic Materials during Liquid Phase Sintering by Numerical-Experimental Procedure

The effective shear and bulk viscosity, as well as dynamic viscosity, describe the rheological properties of the ceramic body during the liquid phase sintering process. The rheological parameters depend on the physical and thermo-mechanical characteristics of the material such as relative density, temperature, grain size, diffusion coefficient, and activation energy. Thermal behavior of the cer...