Analysis of Absorption Spectra of Zinc Porphyrin, Zinc meso-Tetraphenylporphyrin, and Halogenated Derivatives
نویسندگان
چکیده
منابع مشابه
Control over the oxidative reactivity of metalloporphyrins. Efficient electrosynthesis of meso,meso-linked zinc porphyrin dimer.
The electrochemical oxidation of zinc(II) 5,15-p-ditolyl-10-phenylporphyrin at its first oxidation potential leads to the formation of the corresponding meso-meso porphyrin dimer as the main product. The number of electrons abstracted, the addition of the hindered base 2,6-lutidine as well as operating in DMF, instead of a CH(2)Cl(2)/CH(3)CN mixture are the key parameters to obtain high yields ...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2002
ISSN: 1089-5639,1520-5215
DOI: 10.1021/jp020053y