An adiabatic model for calculating overtone spectra of dimers such as (H 2 O) 2

An adiabatic model for calculating overtone spectra of dimers such as (H(2)O)(2).

The near-infrared and visible wavelength spectrum of the water dimer is considered to be the major contributor to the so-called water continuum at these wavelengths. However, theoretical models of this spectrum require the simultaneous treatment of both monomer and dimer excitations. A model for treating this problem is proposed which is based upon a Franck-Condon-like separation between the mo...

An adiabatic model for calculating overtone spectra of dimers such as ( H 2 O )

The near-infrared and visible wavelength spectrum of the water dimer is considered to be the major contributor to the so-called water continuum at these wavelengths. However, theoretical models of this spectrum require the simultaneous treatment of both monomer and dimer excitations. A model for treating this problem is proposed which is based upon a Franck–Condon-like separation between the mo...

spectra of dimers such as ( H An adiabatic model for calculating overtone

References related-urls http://rsta.royalsocietypublishing.org/content/370/1968/2656.full.html# Article cited in: l.html#ref-list-1 http://rsta.royalsocietypublishing.org/content/370/1968/2656.ful This article cites 56 articles, 3 of which can be accessed free Subject collections (13 articles) atomic and molecular physics • (39 articles) atmospheric science • collections Articles on similar t...

Overtone vibrational spectroscopy in H 2 - H 2 O complexes : A combined

Kinetics of HO 2 + HO 2 ! H 2 O 2 + O 2 : Implications for Stratospheric H

[1] The reaction HO2 + HO2 ! H2O2 + O2 (1) has been studied at 100 Torr and 222 K to 295 K. Experiments employing photolysis of Cl2/CH3OH/O2/N2 and F2/H2/O2/N2 gas mixtures to produce HO2 confirmed that methanol enhanced the observed reaction rate. At 100 Torr, zero methanol, k1 = (8.8 ± 0.9) 10 13 exp[(210 ± 26)/T] cm molecule 1 s 1 (2s uncertainties), which agrees with current recommendations...