Aluminum incorporation in MCM-41 mesoporous molecular sieves
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چکیده
منابع مشابه
Templated Growth of Carbon Nanotubes on Nickel Loaded Mesoporous MCM-41 and MCM-48 Molecular Sieves
Chemical vapor deposition was employed to synthesize carbon nanotubes with Ni-loaded MCM-41 and MCM-48 as catalysts and acetylene as precursor at 750°C. Mesoporous Ni MCM-41 and Ni MCM-48 molecular sieves were synthesized by a hydrothermal method and were characterized by XRD and N2 adsorption isotherm. The catalytically synthesized carbon materials were characterized with Raman spectroscopy, N...
متن کامل"Tubules-Within-a-Tubule" Hierarchical Order of Mesoporous Molecular Sieves in MCM-41
The recently discovered mesoporous aluminosilicate MCM-41 consists of hexagonal arrays of nanometer-sized cylindrical pores. It is shown that this material can be synthesized by cooperative condensation of silicate and cylindrical cationic micelles. Careful control of the surfactant-water content and the rate of condensation of silica at high alkalinity resulted in hollow tubules 0.3 to 3 micro...
متن کاملHoveyda–Grubbs type metathesis catalyst immobilized on mesoporous molecular sieves MCM-41 and SBA-15
A commercially available Hoveyda-Grubbs type catalyst (RC303 Zhannan Pharma) was immobilized on mesoporous molecular sieves MCM-41 and on SBA-15 by direct interaction with the sieve wall surface. The immobilized catalysts exhibited high activity and nearly 100% selectivity in several types of alkene metathesis reactions. Ru leaching was found to depend on the substrate and solvent used (the low...
متن کاملtemplated growth of carbon nanotubes on nickel loaded mesoporous mcm-41 and mcm-48 molecular sieves
chemical vapor deposition was employed to synthesize carbon nanotubes with ni-loaded mcm-41 and mcm-48 as catalysts and acetylene as precursor at 750°c. mesoporous ni mcm-41 and ni mcm-48 molecular sieves were synthesized by a hydrothermal method and were characterized by xrd and n2 adsorption isotherm. the catalytically synthesized carbon materials were characterized with raman spectroscopy, n...
متن کاملModified Titanium Content in Titanosilicates Mesoporous Molecular Sieves MCM-41 as Selective Catalyst for Epoxidation of Alkenes
Ti-MCM-41 was synthesized at pH 3, 7 and 11. The titanium content was determined by AAS and found to be 4%, 3.2% and 4.5%, respectively. In order to increase the titanium content in Ti-MCM-41, Ti(IV) ions were grafted onto Ti-MCM-41 using TiCl4 in toluene and Ti(OBu)4 in ethanol. The incorporation of Ti was determined to be 28% and 30%, respectively. The oxidation of olefins such as cyclopenten...
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ژورنال
عنوان ژورنال: Microporous Materials
سال: 1995
ISSN: 0927-6513
DOI: 10.1016/0927-6513(95)00063-1