Aluminium-catalysed isocyanate trimerization, enhanced by exploiting a dynamic coordination sphere
نویسندگان
چکیده
منابع مشابه
Synthesis of Cyclic Carbonates Catalysed by Aluminium Heteroscorpionate Complexes.
New aluminium scorpionate based complexes have been prepared and used for the synthesis of cyclic carbonates from epoxides and carbon dioxide. Bimetallic aluminium(heteroscorpionate) complexes 9-14 were synthesised in very high yields. The single-crystal X-ray structures of 12 and 13 confirm an asymmetric κ(2)-NO-μ-O arrangement in a dinuclear molecular disposition. These bimetallic aluminium c...
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2019
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c9cc03339d