Adiabatic demagnetization cooling well below the magnetic ordering temperature in the triangular antiferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mrow><mml:mi>KBaGd</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>BO</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math>

نویسندگان
چکیده

Crystal structure, thermodynamic properties, and adiabatic demagnetization refrigeration (ADR) effect in the spin-$\frac{7}{2}$ triangular antiferromagnet $\mathrm{KBaGd}{({\mathrm{BO}}_{3})}_{2}$ are reported. With average nearest-neighbor exchange coupling of 44 mK, this compound shows magnetic order below ${T}_{N}=263$ mK zero field. The ADR tests reach temperature ${T}_{min}=122\phantom{\rule{0.16em}{0ex}}\mathrm{mK}$, more than twice lower ${T}_{N}$, along with entropy storage capacity 192 mJ ${\mathrm{K}}^{\ensuremath{-}1}$ ${\mathrm{cm}}^{\ensuremath{-}3}$ hold time 8 h PPMS setup, both significantly improved compared to spin-$\frac{1}{2}\phantom{\rule{4pt}{0ex}}{\mathrm{Yb}}^{3+}$ analog. We argue that a balanced interplay dipolar couplings together structural randomness geometrical frustration shift ${T}_{min}$ well ordering therefore facilitating cooling.

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ژورنال

عنوان ژورنال: Physical review

سال: 2023

ISSN: ['2469-9950', '2469-9969', '2469-9977']

DOI: https://doi.org/10.1103/physrevb.107.104402