A Well-Defined Terminal Vanadium(III) Oxo Complex

A well-defined terminal vanadium(III) oxo complex.

The ubiquity of vanadium oxo complexes in the V+ and IV+ oxidation states has contributed to a comprehensive understanding of their electronic structure and reactivity. However, despite being predicted to be stable by ligand-field theory, the isolation and characterization of a well-defined terminal mononuclear vanadium(III) oxo complex has remained elusive. We present the synthesis and charact...

Mitochondrial Haplogroups and Well Defined Populations

An asymptomatic well-defined brown coloured plaque on the eyebrow in a middle aged woman

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Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes**

A Rh-catalyst system based on the asymmetric ligand (t)Bu2PCH2P(o-C6H4OMe)2 is reported that allows for the hydroacylation of challenging internal alkenes with β-substituted aldehydes. Mechanistic studies point to the stabilizing role of both excess alkene and the OMe-group.

Reduction by well-defined objectives.

Examination of programmes of experimental work involving live animals indicates scope for worthwhile reduction in animal usage by identifying more clearly the objectives of the different stages of a programme. Having a defined first objective for new or transferred methodology as "to optimise the methods", rather than an exploratory "try it with a few animals and modify" approach, is more likel...