A qualitative reaction of primary and secondary amines
نویسندگان
چکیده
منابع مشابه
A ruthenium racemisation catalyst for the synthesis of primary amines from secondary amines.
A Ru-based half sandwich complex used in amine and alcohol racemization reactions was found to be active in the splitting of secondary amines to primary amines using NH3. Conversions up to 80% along with very high selectivities were achieved. However, after about 80% conversion the catalyst lost activity. Similar to Shvo's catalyst, the complex might deactivate under the influence of ammonia. I...
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Biomimetic aerobic oxidation of primary benzylic amines has been achieved by using a quinone catalyst. Excellent selectivity is observed for primary, unbranched benzylic amines relative to secondary/tertiary amines, branched benzylic amines, and aliphatic amines. The exquisite selectivity for benzylic amines enables oxidative self-sorting within dynamic mixtures of amines and imines to afford h...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1960
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.9.26