A practical method for measuring the true hydroxide conductivity of anion exchange membranes
نویسندگان
چکیده
منابع مشابه
Simultaneous Enhancements of Conductivity and Stability for Anion Exchange Membranes (AEMs) through Precise Structure Design
Polymeric materials as anion exchange membranes (AEMs) play an essential role in the field of energy and environment. The achievement of high performance AEMs by the precise manipulation of macromolecular architecture remains a daunting challenge. Herein, we firstly report a novel rod-coil graft copolymer AEM, possessing rigid hydrophobic main chains and soft hydrophilic graft chains. The low g...
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Polyethersulfone (PES)-based anion exchange blend membranes were prepared from quaternized-PES (Q-PES) and N-Methyl-2-pyrrolidone (NMP) casting solutions with water as coagulant via non-solvent induced phase inversion. The compatibility of the blend system was investigated through thermodynamic studies while membrane formation was determined using the cloud point techni...
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The transport properties of various anion and cation exchange membranes were studied in different electrolyte solutions using chronopotentiometry technique to get insight about the influence of the counter ion on the transport properties of the membranes. The investigated samples include heterogeneous ion exchange membranes varying in the functionality of fixed charged gro...
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In present research work, anion exchange membranes based on quaternized polysulfone with ammonium cation moieties (QAPSF) were prepared by chloromethylation, amination and alkalization. The chloromethylated polysulfone were characterized by 1HNMR spectroscopy and functionalization degree was determined according to peak area integration. Ion transport properties (ionic conductivity, ion exchang...
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A series of radiation-grafted alkaline anion-exchange membranes (AAEMs) with degrees of grafting (by mass) in the range 20 – 26% were produced and characterised. Conductivities (from impedance spectroscopy) up to 0.023 ± 0.001 S cm at 50 ± 1°C were demonstrated, which are between 20 – 50% of values for the commercial acidform membrane Nafion-115 (σ = 0.045 ± 0.004 (65°C) – 0.104 ± 0.008 (50 ± 1...
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ژورنال
عنوان ژورنال: Electrochemistry Communications
سال: 2018
ISSN: 1388-2481
DOI: 10.1016/j.elecom.2018.01.021