A New Route to (−)-Aristeromycin and (−)-Neplanocin Aviathe Asymmetric Diels–Alder Cycloaddition
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چکیده
منابع مشابه
A catalytic dipolar cycloaddition route to pyrroloimidazoles
A catalytic method involving carbenoid insertion onto dihydroimidazoles is reported for the generation of dihydroimidazolium ylides, and their subsequent diastereoselective cycloaddition to form pyrrolo[1,2-a]imidazoles © 2009 Elsevier Science. All rights reserved ———
متن کاملCycloaddition of homochiral dihydroimidazoles: a 1,3-dipolar cycloaddition route to optically active pyrrolo[1,2-a]imidazoles.
N-Alkylation of optically active 1-benzyl-4-phenyl-4,5-dihydroimidazole with active alkyl halides and treatment of the so-formed 4,5-dihydroimidazolium ions with DBU in the presence of a range of electron-deficient alkene dipolarophiles, constitutes a 'one-pot' cascade terminating in a 1,3-dipolar cycloaddition reaction that affords optically active pyrrolo[1,2-a]imidazoles. Three bonds of the ...
متن کاملA cycloaddition route to novel triazole boronic esters.
The [3 + 2] cycloaddition of alkynylboronates and azides provides a direct route to novel triazole boronic esters, the regioselectivity of this process and functionalisation of the heterocycle products is described.
متن کاملGaCl3-assisted [2 + 3] cycloaddition: a route to tetrazaphospholes.
The GaCl3-assisted [2 + 3] cycloaddition of Mes*-N=P-Cl (Mes* = 2,4,6-tBu3C6H2) with trimethylsilylazide (TMS-N3) results in the formation of the first tetrazaphosphole, stabilized as a GaCl3 adduct in high yields (>96%).
متن کاملa synchronic and diachronic approach to the change route of address terms in the two recent centuries of persian language
terms of address as an important linguistics items provide valuable information about the interlocutors, their relationship and their circumstances. this study was done to investigate the change route of persian address terms in the two recent centuries including three historical periods of qajar, pahlavi and after the islamic revolution. data were extracted from a corpus consisting 24 novels w...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1987
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1987.185