A Flexible and Porous Ferrocene‐Based Gallium MOF with MIL‐53 Architecture

IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings.

Five metal-organic frameworks (MOFs) based on the same three-dimensional gallium terephthalate network (IM-19) are described, and an incommensurate structure (for the as-synthesized form) as well as two remarkable guest-free polymorphs (open and closed) are highlighted.

The first porous MOF with photoswitchable linker molecules.

We synthesized a porous twofold interpenetrated MOF [Zn(2)(NDC)(2)(1)] (coined CAU-5) using 3-azo-phenyl-4,4'-bipyridine (1), 2,6-naphthalenedicarboxylic acid, and Zn(NO(3))(2)·6H(2)O. The azo-functionality protrudes into the pores, and can be switched, by irradiation with UV light (365 nm), from the thermodynamically stable trans-isomer to the cis-isomer. Back-switching was achieved thermally ...

a comparison of teachers and supervisors, with respect to teacher efficacy and reflection

supervisors play an undeniable role in training teachers, before starting their professional experience by preparing them, at the initial years of their teaching by checking their work within the proper framework, and later on during their teaching by assessing their progress. but surprisingly, exploring their attributes, professional demands, and qualifications has remained a neglected theme i...

A flexible code generator for MOF-based modeling languages

The Meta Object Facility (MOF) is the core component of OMGt’s ModelDriven Architecture (MDA). MOF defines the metamodeling language, which is used to define the languages which are used to model apllications, such as the Unified Modeling Language (UML). The importance of MOF will grow in the future, because more and more domain-specific modeling languages will be defined as extensions to or ad...

Fast: a Flexible Architecture