A comprehensive Monte Carlo simulation of styrene atom transfer radical polymerization
نویسندگان
چکیده
منابع مشابه
study of atom transfer radical polymerization of styrene and its gel effect by monte carlo simulation method
atom transfer radical polymerization (atrp) of styrene was carried out at 105°c and a monte carlo simulation was employed to model the system. the variations of monomer conversion, the initiator concentration, average molecular weight, and molecular weight distribution were evaluated as the reaction proceeded. according to the results obtained, for similar reaction time, monomer conversion is h...
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............................................................................................................................. iii Acknowledgments............................................................................................................... v Table of
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A side-on liquid crystalline monomer, 2,5-bis[(4-hexyloxyphenyl)oxycarbonyl]styrene) (HPCS), was successfully polymerized via atom transfer radical polymerization (ATRP). The polymerization was catalyzed by CuBr/PMDETA in chlorobenzene at 90°C with (1-bromoethyl)benzene as the initiator. The polymers have narrow MWD. It is the second example of mesogen-jacketed liquid crystalline polymer (MJLCP...
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ژورنال
عنوان ژورنال: Chinese Journal of Polymer Science
سال: 2010
ISSN: 0256-7679,1439-6203
DOI: 10.1007/s10118-010-9058-1