A calibrated peroxy radical chemical amplifier for ground-based tropospheric measurements
نویسندگان
چکیده
منابع مشابه
Isoprene Peroxy Radical Dynamics.
Approximately 500 Tg of 2-methyl-1,3-butadiene (isoprene) is emitted by deciduous trees each year. Isoprene oxidation in the atmosphere is initiated primarily by addition of hydroxyl radicals (OH) to C4 or C1 in a ratio 0.57 ± 0.03 (1σ) to produce two sets of distinct allylic radicals. Oxygen (O2) adds to these allylic radicals either δ (Z or E depending on whether the allylic radical is cis or...
متن کاملMeasurements of peroxy radicals using chemical amplification-cavity ringdown spectroscopy.
The peroxy radical chemical amplification (PERCA) method is combined with cavity ringdown spectroscopy(CRDS) to detect peroxy radicals (HO2 and RO2). In PERCA, HO2 and RO2 are first converted to NO2 via reactions with NO, and the OH and RO coproducts are recycled back to HO2 in subsequent reactions with CO and O2; the chain reactions of HO2 are repeated and amplify the level of NO2. The amplifi...
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Introduction: Ultraviolet index (UVI) is a dimensionless scale, which describes the maximum intensity and biologic effects of UV during a specific time, on surface of the earth. The UVI is an international standard measurement of the strength of sunburn producing ultraviolet radiation at a particular place and time. This index is an easy and understandable concept for pr...
متن کاملPeroxy radical chemistry at Mace Head, Ireland
Peroxy radical chemistry and the control of ozone photochemistry at Mace Head, Ireland during the summer of 2002 Z. L. Fleming, P. S. Monks, A. R. Rickard, D. E. Heard, W. J. Bloss, P. W. Seakins, T. J. Still, R. Sommariva, M. J. Pilling, R. Morgan, T. J. Green, N. Brough, G. P. Mills, S. A. Penkett, A. C. Lewis, J. D. Lee, A. Saiz-Lopez, and J. M. C. Plane Department of Chemistry, University o...
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ژورنال
عنوان ژورنال: Journal of Geophysical Research: Atmospheres
سال: 1997
ISSN: 0148-0227
DOI: 10.1029/97jd01902