(6-Acetoxy-2-acetylphenyl-κ2 C 1,O 1)tetracarbonylmanganese(I)
نویسندگان
چکیده
منابع مشابه
(Acetoxy)(2-methylphenyl)methyl acetate
In the title compound, C(12)H(14)O(4), the two acet-oxy groups are inclined by 57.92 (5)° and 62.71 (6)° to the benzene ring. An inter-molecular C-H⋯O inter-action involving the two acet-oxy groups generates a centrosymmetric dimer via an R(2) (2)(16) ring motif.
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In the title compound, [Ni(C(8)H(7)O(3))(NO(3))(C(12)H(12)N(2))(2)], the asymmetric unit contains a Ni(II) atom, two mol-ecules of 2-(benzyl-amino)pyridine, a mol-ecule of deprotonated o-vanillin (3-methoxy-salicylaldehydate) and a bidentate nitrate anion. The Ni(II) center is six-coordinated by two pyridine N atoms from 2-(benzyl-amino)pyridine, two O atoms from o-vanillin and two O atoms from...
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Two ent-18-acetoxy-6-oxomanoyl oxides, epimers at C-13, have been prepared from ent-6alpha,8alpha,18-trihydroxylabda-13(16),14-diene (andalusol), isolated from Sideritis foetens, by means of several chemical pathways and a regioselective acylation with Candida cylindracea lipase (CCL). Biotransformation of these 13-epimeric ent-manoyl oxides by Fusarium moniliforme and Neurospora crassa produce...
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The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra-molecular C-H⋯O inter-action is noted. The crystal studied was a racemic twin.
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The title compound, [Ir(C(12)H(8)NO)Cl(2)(C(12)H(9)NO)]·CH(2)Cl(2), which was obtained from the reaction of iridium(III) chloride trihydrate and 2-benzoyl-pyridine, contains an Ir(III) atom coordinated by two N, one O, one C and two Cl atoms in trans positions, forming a distorted octa-hedral environment. The solvent molecule CH(2)Cl(2) is disordered over two positions with an occupancy of 0.8:...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2007
ISSN: 1600-5368
DOI: 10.1107/s1600536807047605