57Fe Mössbauer studies on natural chromites
نویسندگان
چکیده
منابع مشابه
Theoretical 57Fe Mössbauer spectroscopy: isomer shifts of [Fe]-hydrogenase intermediates.
Mössbauer spectroscopy is an indispensable spectroscopic technique and analytical tool in iron coordination chemistry. The linear correlation between the electron density at the nucleus ("contact density") and experimental isomer shifts has been used to link calculated contact densities to experimental isomer shifts. Here we have investigated relativistic methods of systematically increasing so...
متن کاملCharacterization of superconducting Bi2Sr2Can-1CunO4+2n phases with 57Fe Mössbauer spectroscopy.
Rights: © 1990 American Physical Society (APS). This is the accepted version of the following article: Tittonen, I. & Hietaniemi, J. & Huttunen, J. & Lindén, J. & Katila, T. & Karlemo, T. & Karppinen, Maarit & Niinistö, L. & Ullakko, K. 1990. Characterization of superconducting Bi2Sr2Can-1CunO4+2n phases with 57Fe Mössbauer spectroscopy. Physical Review B. Volume 42, Issue 7. 4212-4218. ISSN 15...
متن کاملMössbauer Spectroscopy and X-ray Diffraction Study of 57Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids
Four (57)Fe-labeled tetrachloroferrates(III) of organic cations (1-butyl-3-methylimidazolium, 1-allyl-3-methylimidazolium, 1-methyl-1-propylpyrrolidinium, tetraphenylphosphonium) were examined by temperature-dependent Mössbauer spectroscopy. The hyperfine and dynamic parameters of the iron(III) site were determined. Single crystal X-ray diffraction data of [Ph(4)P][FeCl(4)] were collected at fo...
متن کاملDensity Functional Calculations for Prediction of 57Fe Mössbauer Isomer Shifts and Quadrupole Splittings in β-Diketiminate Complexes
The relative ease of Mössbauer spectroscopy and of density functional theory (DFT) calculations encourages the use of Mössbauer parameters as a validation method for calculations, and the use of calculations as a double check on crystallographic structures. A number of studies have proposed correlations between the computationally determined electron density at the iron nucleus and the observed...
متن کاملHyperfine structure of (57Fe) iron in the Mössbauer spectrum of the high-potential iron protein from Chromatium.
The magnetic hyperfine structure observed in the (57)Fe Mössbauer spectra of the high-potential iron protein from Chromatium shows that the iron atoms are inequivalent in pairs, with hyperfine fields of 121 and 90kG.
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ژورنال
عنوان ژورنال: Bulletin of Materials Science
سال: 1996
ISSN: 0250-4707,0973-7669
DOI: 10.1007/bf02744643