4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine

نویسندگان

چکیده

Dibromoderivatives of benzofused chalcogen-nitrogen heterocycles are important precursors in the synthesis various photovoltaic materials. 4,7-Dibromobenzo[d][1,2,3]thiadiazole is a practically unexplored compound this series. In communication, it was shown that nucleophilic substitution 4,7-dibromobenzo[d][1,2,3]thiadiazole with morpholine gave selectively 4-substituted product—4-(7-bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine. The structure newly synthesized established by means elemental analysis, high resolution mass-spectrometry, 1H, 13C NMR, and IR spectroscopy, X-ray analysis.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

7-Chloro-4-[(7-chloro­quinolin-4-yl)sulfan­yl]quinoline dihydrate

In the title thio-ether dihydrate, C(18)H(10)Cl(2)N(2)S·2H(2)O, the S-bound quinolinyl residues are almost orthogonal, forming a dihedral angle of 72.36 (4)°. In the crystal, the four water mol-ecules are connected via an eight-membered {⋯OH}(4) synthon with each of the four pendent water H atoms hydrogen bonded to a pyridine N atom to stabilize a three-dimensional architecture.

متن کامل

4-[(7-Fluoro­quinazolin-4-yl)­oxy]aniline

In the mol-ecule of the title compound, C(14)H(10)FN(3)O, the bicyclic quinazoline system is effectively planar, with a mean deviation from planarity of 0.0140 (3) Å. The quinazoline heterocyclic system and the adjacent benzene ring make a dihedral angle of 85.73 (9)°. Two inter-molecular N-H⋯N hydrogen bonds contribute to the stability of the crystal structure. In addition, a weak π-π stacking...

متن کامل

KbP 23 . 1 - 9 . 4 - 6 . 7 - 4 . 4 - 2 .

The gene for the prototype acute phase reactant, Creactive protein, has been isolated from two X phage libraries containing inserted human DNA fragments using synthetic oligonucleotide probes. Nucleotide sequence analysis indicates that after coding for a signal peptide of 18 amino acids and the first two amino acids of the mature protein, there is an intron of 278 base pairs followed by the nu...

متن کامل

4–7 September 2014

Aim: To assess whether intensity modulated radiotherapy (IMRT) offers any advantages compared to three-dimensional conformal radiotherapy (3DCRT) when treating the ilio-inguinal lymph-node basin after therapeutic lymphadenectomy for melanoma. Method: 15 consecutive patients receiving adjuvant radiotherapy (48 Gy in 20 fractions) were selected for the study. Simulation, volume generation and goa...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Molbank

سال: 2021

ISSN: ['1422-8599']

DOI: https://doi.org/10.3390/m1202