4′-[2-(Trifluoromethyl)phenyl]-2,2′:6′,2′′-terpyridine

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4′-[4-(Pyridin-2-yl)phen­yl]-2,2′:6′,2′′-terpyridine

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Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate

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[4′-(4-Amino­phen­yl)-2,2′:6′,2′′-terpyridine]­chloridopalladium(II) chloride

The Pd(II) atom in the complex cation of the title compound, [PdCl(C(21)H(16)N(4))]Cl, is coordinated by three N atoms derived from the terpyridine ligand and a chloride ion, which define a distorted PdClN(3) square-planar coordination geometry. In the crystal, the presence of N-H⋯Cl hydrogen bonds involving the amino H atom and chloride anions link two cations and two anions into a four-ion ag...

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4′-[2-(Trifluoro­meth­yl)phen­yl]-2,2′:6′,2′′-terpyridine

The title compound, C(22)H(14)F(3)N(3), is a versatile tridentate N-donor ligand consisting of a terpyridyl (terpy) molecule substituted in the 4'-position by a phenyl group, itself substituted in an ortho-position by a bulky trifluoro-methyl group. The phenyl ring is twisted as a result of steric inter-actions involving the bulky trifluoro-methyl substituent. This is reflected in the dihedral ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809002384