3,9′-Bi(9H-fluorene)

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3,9′-Bi(9H-fluorene)

THE TITLE COMPOUND [SYSTEMATIC NAME: 9-(9H-fluoren-3-yl)-9H-fluorene], C(26)H(18), was obtained unintentionally as the product of the synthesis of a compound based on fluorene-thio-phene units. The two fluorene rings are connected through C atoms in the 3- and 9'-positions, and the dihedral angle between the mean planes of the two fluorene units is 78.57 (6)°.

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Ethynylene - bridged Porphyrin Fluorene Composites

Porphyrin-fluorene conjugates bridged by ethynylene were synthesized through Pd-catalyzed cross-coupling reaction. These molecules showed strong nonlinear absorption when measured using a nanosecond Z-scan method. The largest effective two-photon absorption cross-section was observed for trisporphyrin as 2.7 × 105 GM at 760 nm, which was 10 times larger than that obtained for monoporphyrin. INT...

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2,7-Dichloro-4-(chloro­acet­yl)fluorene

There are two mol-ecules in the asymmetric unit of the title compound, C(15)H(9)Cl(3)O. The fluorene rings of the two mol-ecules are both coplanar within 066 (3) Å. In the crystal, C-H⋯O and C-H⋯Cl hydrogen bonds link the mol-ecules into sheets running parallel to (100).

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A series of star-shaped oligofluorene molecules, each containing a TPE core, have been specifically designed and produced to show effective aggregation-induced emission (AIE). Each molecule differs either in the number of fluorene units within the arms (e.g., 1 or 4, compounds 4 and 5), or the terminal group positioned at the end of each arm (e.g., H, TMS, or TPA, compounds 4, 6, and 7). Althou...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812024841