3-Bromopyridin-2-amine

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3-Benzyl­oxypyridin-2-amine

In the title compound, C(12)H(12)N(2)O, the dihedral angle between the planes of the pyridine and phenyl rings plane is 35.94 (12)°. In the crystal structure, centrosymmetrically related mol-ecules are linked by a pair of N-H⋯N hydrogen bonds, forming a dimer with an R(2) (2)(8) ring motif. In addition, there is an intra-molecular N-H⋯O inter-action.

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3-Bromo­pyridin-2-amine

In the crystal structure of the title compound, C(5)H(5)BrN(2), mol-ecules assemble via pairs of N-H⋯N hydrogen bonds into inversion dimers using only the syn H atom on the amine group. These dimers then assemble further into two-dimensional layers via type I C-Br⋯Br [Br⋯Br = 3.693 (s6) Å] halogen bonding along the (102) plane.

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3-Chloro­pyridin-2-amine

In the title compound, C(5)H(5)ClN(2), a by-product in the synthesis of ethyl 2-(3-chloro-pyridin-2-yl)-5-oxopyrazolidine-3-carboxyl-ate, the amine groups form inter-molecular hydrogen-bonding associations with pyridine N-atom acceptors, giving centrosymmetric cyclic dimers. Short inter-molecular Cl⋯Cl inter-actions [3.278 (3) Å] also occur.

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N-(3-Chloro­phen­yl)-3-nitro­pyridin-2-amine

The dihedral angle between the benzene and pyridyl rings in the title compound, C(11)H(8)ClN(3)O(2), is 22.65 (10)°, indicating a twisted mol-ecule. The amine H and nitro O atoms form a donor-acceptor pair for an intra-molecular N-H⋯O hydrogen bond so that the nitro group is almost coplanar with the pyridine ring to which it is connected [O-N-C-C torsion angle = 7.4 (3)°]. The pyridine N and Cl...

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3-Chloro-5-(trifluoro­meth­yl)pyridin-2-amine

In the title compound, C(6)H(4)ClF(3)N(2), an inter-mediate in the synthesis of the fungicide fluazinam, the F atoms of the trifluoro-methyl group are disordered over two sites in a 0.683 (14):0.317 (14) ratio. In the crystal structure, centrosymmetric dimers arise from pairs of N-H⋯N hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536811055541