منابع مشابه
2H Isotope Effect on 13C Chemical Shifts of Nitro-Benzo-9-Crown-3
Deuterium substitution on two ortho-substituted-OCH2-fragments in Nitro-Benzo-9-Crown-3 induces low frequency shifts, positive mnDCj, in all 13C NMR resonances which is an indication of the increased shielding in this crown ether. The magnitude of these shifts vary from 15DC7=716 to 54D<...
متن کاملNew Hybrid Nanomaterial Derived from Immobilization of 4-Formyl Benzo-9-Crown-3 Ether onto the Mesopores of MCM-41
In this work, we report a new hybrid nanomaterial based on the immobilization of 4-formyl benzo-9-crown-3 ether (FB9C3) onto the mesopores of MCM-41. First, the mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl triethoxysilane to give aminopropyl modified MCM-41 (AmpMCM-41). Reaction of this material with FB9C3 afforded the B9C3-AmpMCM-41 hybrid nanomaterial. The prepa...
متن کامل2h isotope effect on 13c chemical shifts of nitro-benzo-9-crown-3
deuterium substitution on two ortho-substituted-och2-fragments in nitro-benzo-9-crown-3 induces low frequency shifts, positive mndcj, in all 13c nmr resonances which is an indication of the increased shielding in this crown ether. the magnitude of these shifts vary from 15dc7=716 to 54dc3=15 ppb for c7 and c3 cd3cocd3, and c6d6 on mndcj values were investigated. the mndcj values depended more o...
متن کاملHydration to benzo-15-crown-5, benzo-18-crown-6 and the benzo-18-crown-6-potassium ion complex in the low-polar organic solvents.
The coextraction of water with benzo-15-crown-5 (B1SC5), benzo-18-crown-6 (B18C6) and the B18C6-K+ complex into seven low-polar solvents, i.e., carbon tetrachloride (CTC), chloroform (CF), dichloromethane (DCM), 1,2-dichloroethane (1,2-DCE), benzene (BZ), chlorobenzene (CB) and o-dichlorobenzene (o-DCB), has been investigated. The mean hydration number, nH2O, of these solutes in the water-satur...
متن کاملAnomalous fluorescent responses of 9-fluorenecarboxamide derivatives possessing benzo-15-crown-5.
A new fluorescent ionophore for alkaline earth metal ions, 4'-(9-fluorenecarboxamido)benzo-15-crown-5 (3), was synthesized; its photochemical behavior was investigated using UV, fluorescence, (1)H NMR, and (13)C NMR spectrometry. In the absence of a metal ion, the fluorene moiety showed weak fluorescence emission (fluorescence "Off" state). However, complexation with metal ions greatly enhanced...
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ژورنال
عنوان ژورنال: Molecules
سال: 2000
ISSN: 1420-3049
DOI: 10.3390/m175