(2-Hydroxy-7-methoxynaphthalen-1-yl)(phenyl)methanone
نویسندگان
چکیده
منابع مشابه
(4-Chlorophenyl)(2-hydroxy-7-methoxynaphthalen-1-yl)methanone
The title compound, C(18)H(13)ClO(3), has an intra-molecular O-H⋯O=C hydrogen bond between the carbonyl group and the hydr-oxy substituent on the naphthalene ring system. The angle between the C=O bond plane and the naphthalene ring system is relatively small [20.96 (8)°]. The angle between the benzene ring and the carbonyl group is rather large [35.65 (9)°] compared to that in an analogous com...
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An efficient synthesis of the 1-hydroxy-2-(prop-2'-enyl)9-anthrone is described. Selective nitration of anthraquinone, reduction to the corresponding amine, diazotization and treatment by sulfuric acid solution afforded the 1-hydroxy-9,10-anthraquinone in good yield as the key intermediate. Reaction with allyl bromide/K2CO3 and subsequent selective reduction accompanie...
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In the title compound, C(20)H(18)N(2)O(2), the mean planes of the naphthyl system and the benzene ring form a dihedral angle of 88.48 (10)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into C(4) chains, which propagate along the b-axis direction.
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Ligands of the aroylhydrazone class have shown much promise as potential chelators for treatment of iron overload disease and perhaps cancer (Johnson et al., 1982; Baker et al., 1992; Richardson et al., 1995; Richardson & Milnes, 1997). Our previous investigations have demonstrated that 2-hydroxy-1naphthaldehyde isonicotinoyl hydrazone, (II), and several other aroylhydrazone chelators possess a...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810038547