2-Ethyl-6-methylanilinium 4-methylbenzenesulfonate

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2-Ethyl-6-methyl­anilinium 4-methyl­benzene­sulfonate

The title compound, C(9)H(14)N(+)·C(7)H(7)SO(3) (-), contains a 2-ethyl-6-methyl-anilinium cation and a 4-methyl-benzene-sulfonic anion. The cations are anchored between the anions through N-H⋯O hydrogen bonds. Electrostatic and van der Waals inter-actions, as well as hydrogen bonds, maintain the structural cohesion.

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(S)-Ethyl 2-[4-(6-chloro­quinoxalin-2-yl­oxy)phen­oxy]propanoate

In the mol-ecule of the title compound, C(19)H(17)ClN(2)O(4), the quinoxaline ring system is planar [maximum deviation = 0.013 (3) Å] and oriented at a dihedral angle of 80.18 (3)° with respect to the benzene ring. In the crystal structure, inter-molecular C-H⋯N inter-actions link mol-ecules into chains. π-π contacts between the quinoxaline systems [centroid-centroid distance = 3.654 (1) Å] may...

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(±)-Ethyl 6-(6-meth­oxy-2-naphth­yl)-4-(4-methyl­phen­yl)-2-oxocyclo­hex-3-ene-1-carboxyl­ate

In the title compound, C(27)H(26)O(4), the dihedral angle between the naphthalene ring system and the benzene ring is 73.10 (5)°. In the crystal, a weak C-H⋯O inter-action occurs. Two C-H groups of the cyclo-hexene ring are disordered over two sets of sites in a 0.796 (5):0.204 (5) ratio, which corresponds to partial overlap of the two enanti-omeric mol-ecules.

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Ethyl 6-(6-meth­oxy­naphthalen-2-yl)-4-(naphthalen-2-yl)-2-oxocyclo­hex-3-ene-1-carboxyl­ate

The title compound, C30H26O4, contains an oxo-cyclo-hexane ring in a distorted half-chair configuration, with disorder of two C atoms in a 0.859 (4):0.141 (4) ratio. The dihedral angle between the mean planes of the two napthalene ring systems is 58.6 (8)°.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s160053680900230x