2-[1-(9-Anthrylmethyl)-1H-pyrazol-3-yl]pyridine

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2-[1-(9-Anthrylmeth­yl)-1H-pyrazol-3-yl]pyridine

The title compound, C(23)H(17)N(3), can be used in coordination chemistry. The anthracene ring makes dihedral angles of 86.08 (5) and 76.63 (6)°, respectively, with the pyridine and pyrazole rings. The dihedral angle between the pyrazole and pyrimidine rings is 11.79 (7)°. In the structure, weak inter-molecular C-H⋯N hydrogen bonds are observed.

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3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate

In the title compound, C(33)H(25)N(2) (+)·PF(6) (-), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40 (3) and 71.39 (4)°, respectively. The crystal structure is stabilized by intermolecular C-H⋯F hydrogen bonding. Four F atoms of the hexa-fluoro-phosphate anion are disordered over two sets of sites in a 0.645 (4):0.355 (4) ...

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3-[3-(2-Pyrid­yl)-1H-pyrazol-1-yl]propan­amide

In the title compound, C(11)H(12)N(4)O, the pyrazole and pyridine rings are nearly coplanar [dihedral angle = 1.87 (5)°]. Adjacent mol-ecules are linked by N-H⋯N and N-H⋯O hydrogen bonds into a linear chain running along the c axis.

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1-[3-(Anthracen-9-yl)-5-(pyridin-2-yl)-4,5-dihydro-1H-pyrazol-1-yl]ethanone

In the title compound, C(24)H(19)N(3)O, the pyrazoline ring adopts an envelope conformation with the C atom linking to the pyridine ring as the flap. The mean plane of the pyrazoline ring makes dihedral angles of 85.54 (4) and 81.66 (3)° with the pyridine ring and the anthracene ring system, respectively. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds. In addition, weak π-π inter...

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2-[3-(Pyridin-1-ium-2-yl)-1H-pyrazol-1-yl]-6-[3-(pyridin-2-yl)-1H-pyrazol-1-yl]pyridinium sulfate methanol monosolvate

The title solvated salt, C21H17N7 (2+)·SO4 (2-)·CH3OH, was obtained when we attempted to prepare the complex of ferrous sulfate and 2,6-bis-[3-(pyridin-2-yl)-1H-pyrazol-1-yl]pyridine in methanol. The dihedral angles between adjacent pyridine and pyrazole rings range from 3.8 (1) to 13.4 (1)°. An intra-molecular N-H⋯N hydrogen bond occurs. In the crystal, N-H⋯O and O-H⋯N hydrogen bonds between s...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809039427