1,3,3,3′,3′-Pentaisopropyl-1,3,3′,6,6′,7,7′-heptahydro-1λ5-1,1′-spirobi[acenaphtho 5,6-cd][1,2,6]oxadiphosphinine]-3,3′-diium Triiodide
نویسندگان
چکیده
Reaction of bis(peri-substituted) triphosphine iPrP(AcenapPiPr2)2 (Acenap = acenaphthene-5,6-diyl) with iodine, followed by hydrolysis, afforded ionic species [iPrP(AcenapP(O)iPr2)2] dication, containing P-O-P-O-P motif, balanced triiodide anions. The new were fully characterised, including single crystal X-ray diffraction. formation the unusual double-bridged motif is likely a result crowding in peri-region.
منابع مشابه
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ژورنال
عنوان ژورنال: Molbank
سال: 2022
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1523