(125)Synthesis of Salicylaldehyde

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4-(Diethyl­amino)salicylaldehyde phenyl­sulfonyl­hydrazone

In the title compound, C(17)H(21)N(3)O(3)S, the dihedral angle between the aromatic ring planes is 84.2 (2)°. The pendant ethyl groups of the -N(C(2)H(5))(2) group are disordered over two sets of positions in a 0.84 (2):0.16 (2) ratio. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond, and inter-molecular N-H⋯O bonds lead to [010] chains in the crystal structure.

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An ortho­rhom­bic polymorph of 5-[(4-methyl­phen­yl)diazen­yl]salicylaldehyde

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ژورنال

عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan

سال: 1952

ISSN: 0023-2734,2185-0860

DOI: 10.1246/nikkashi1898.55.258