1,2-Di(arylmethylidene)cycloalkanes; the Conformation of Non-transoid Conjugated Dienes.
نویسندگان
چکیده
منابع مشابه
Cyclopolymerization of Conjugated Dienes
The formation of essentially saturated polymers containing fused cyclohexane rings is a characteristic of the polymerization of conjugated dienes under the influence of all cationic or Lewis acid catalysts. The amount of cyclic structures and non-terminal linear unsaturation is dependent upon the electron accepting ability of the catalyst, which may be greatly influenced by the nature of the so...
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Selective 1,2-hydrosilylation of 1,3-dienes is a challenging problem in transition metal catalysis. Butadiene, specifically, would be a useful substrate because 3-butenylsilane products have promise as superior coupling reagents for hybrid organic/inorganic materials synthesis. We report the first selective 1,2-hydrosilylation of conjugated dienes including butadiene. Hydrosilylation proceeds t...
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the present study was carried out to investigate the effect of various refining processes’ conditions on conjugated dienes in soybean oil. conjugated dienes contents of soybean oil were found to undergo reduction in neutralization and bleaching steps while being increased in deodorization. it was observed that alkali refining (neutralization) through 12 and 14 °bé, bleaching with either acid ac...
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The hetero-Diels-Alder reaction between a nitroso dienophile and a conjugated diene to give the 3,6-dihydro-2H-1,2-oxazine scaffold is useful for the synthesis of many biologically interesting molecules due to the diverse opportunities created by subsequent transformations of the resulting 1,2-oxazine ring. This review discusses the rationale for the observed regio- and stereoselectivity and th...
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Pd-catalyzed aerobic oxidative coupling of vinylboronic acids and electronically unbiased alkyl olefins provides regioselective access to 1,3-disubstituted conjugated dienes. Catalyst-controlled regioselectivity is achieved by using 2,9-dimethylphenanthroline as a ligand. The observed regioselectivity is opposite to that observed from a traditional (nonoxidative) Heck reaction between a vinyl b...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1972
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.26-0961