113 ASPARTATE ISOMERIZATION IN OSTEOARTHRITIS

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Kinetics of Isomerization and Inversion of Aspartate 58 of aA-Crystallin Peptide Mimics under Physiological Conditions

Although proteins consist exclusively of L-amino acids, we have reported that aspartyl (Asp) 58 and Asp 151 residues of aAcrystallin of eye lenses from elderly cataract donors are highly inverted and isomerized to D-b, D-a and L-b-Asp residues through succinimide intermediates. Of these Asp isomers, large amounts of D-band L-b-isomers are present but the amount of D-a-isomer is not significant....

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Kinetics of Isomerization and Inversion of Aspartate 58 of αA-Crystallin Peptide Mimics under Physiological Conditions

Although proteins consist exclusively of L-amino acids, we have reported that aspartyl (Asp) 58 and Asp 151 residues of αA-crystallin of eye lenses from elderly cataract donors are highly inverted and isomerized to D-β, D-α and L-β-Asp residues through succinimide intermediates. Of these Asp isomers, large amounts of D-β- and L-β-isomers are present but the amount of D-α-isomer is not significa...

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ژورنال

عنوان ژورنال: Osteoarthritis and Cartilage

سال: 2007

ISSN: 1063-4584

DOI: 10.1016/s1063-4584(07)61746-4