10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine

نویسندگان

چکیده

The UV light-mediated metal-free polymerizations of 4-vinylpyridine (4VP) have been successfully performed by using 10-(pyren-1-yl)-10H-phenothiazine (PPTh) and pyrene as photocatalysts. preparation narrow polydispersity poly (4-vinyl pyridine) (P4VP) with high conversions was enabled in both protic well unprotic reaction media at ambient temperature. Additionally, copolymerizations 4VP acrylate methacrylate monomers were also demonstrated, affording copolymer products.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

1-(10H-phenothia­zin-10-yl)ethanone

In the title compound, C14H11NOS, the phenothia-zine unit has a butterfly conformation and the central six-membered ring has a boat form. The fold angle between the benzene rings is 46.39 (7)°, which is larger than found in similar compounds, probably as a result of steric repulsion between the phenothia-zine fragment and the acetyl group.

متن کامل

10-(Prop-1-yn-1-yl)-10H-phenothia­zine

In the title compound, C(15)H(11)NS, the asymmetric unit comprises one half-mol-ecule; a mirror plane passes through the S atom, the ynamine fragment, the methyl C atom and one methyl H atom. The phenothia-zine moiety has a butterfly conformation and the central six-membered ring has a boat conformation. The dihedral angle between the benzene rings is 149.40 (4)°. The crystal structure is stabi...

متن کامل

4-Aryl-2, 6-di(pyren-1-yl)pyridines: A facile procedure for synthesis and studying of fluorescence properties

Pyrene and its derivatives exhibit thermal stability, high extinction coefficients, excimer formation, high photoluminescence, long fluorescence lifetime, fluorophoric properties and enhanced charge carrier mobility which make them find applications in optoelectronic area and are useful as large planar synthetic building blocks in supramolecular chemistry. One of the approaches to overcome this...

متن کامل

1-(5,5-Dioxido-10H-phenothia­zin-10-yl)ethanone

In the title compound, C(14)H(11)NO(3)S, the six-membered thia-zine ring fused to two benzene rings adopts a distorted boat conformation. The dihedral angle between the mean planes of the two benzene rings is 45.8 (1)°. The crystal packing is stabilized by weak inter-molecular C-H⋯O inter-actions.

متن کامل

N,N-Dimethyl-4-(pyren-1-yl)aniline

In the title compound, C24H19N, the di-methyl-amino group is inclined to the benzene ring by 2.81 (9)°. Their mean plane makes a dihedral angle of 64.12 (2)° with the mean plane of the pyrene ring system [r.m.s. deviation = 0.031 (1) Å]. In the crystal, mol-ecules are linked via C-H⋯π inter-actions, which connect neighbouring mol-ecules into columns along the c axis.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Polimeros-ciencia E Tecnologia

سال: 2021

ISSN: ['0104-1428', '1678-5169', '1984-7386']

DOI: https://doi.org/10.1590/0104-1428.08120