1-(Pyridin-2-yl)-2-[2-(trifluoromethyl)benzyl]-3-[2-(trifluoromethyl)phenyl]propan-1-one

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1-(Pyridin-2-yl)-2-[2-(trifluoro­meth­yl)benz­yl]-3-[2-(trifluoro­meth­yl)phen­yl]propan-1-one

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The mean planes of the benzene and pyridine rings in the title compound, C(15)H(12)BrNO(2), are nearly coplanar, subtending an angle of 2.8 (8)°. The prop-2-en-1-one group is also in the plane of these rings with an N-C-C-O torsion angle of 179.6 (3)°. A weak C-H⋯Br inter-molecular inter-action contributes to the crystal packing, creating a chain-like structure along the a axis.

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In the title compound, C(29)H(25)N(3)O, the central imidazole ring forms dihedral angles of 64.7 (3), 33.5 (3) and 81.2 (2)° with the pyridyl and two phenyl substituents, respectively. An intra-molecular C-H⋯N hydrogen bond is observed. In the crystal, O-H⋯N and C-H⋯O hydrogen bonds link the mol-ecules into chains parallel to the a axis.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812003698