1-Chloroacetyl-3-isopropyl-r-2,c-6-diphenylpiperidin-4-one
نویسندگان
چکیده
منابع مشابه
r-2,c-6-Bis(4-chlorophenyl)-t-3-isopropyl-1-nitrosopiperidin-4-one
In the title mol-ecule, C(20)H(20)Cl(2)N(2)O(2), the piperidine ring adopts a chair conformation and the nitroso group at position 1 has a bis-ectional orientation. The two benzene rings and the isopropyl group attached to the piperidine ring in positions 2, 6 and 3, respectively, have axial orientations. The dihedral angle between the two benzene rings is 21.56 (13)°. One of the Cl atoms is di...
متن کامل1-Dichloroacetyl-t-3-isopropyl-r-2,c-6-diphenylpiperidin-4-one
In the title compound, C22H23Cl2NO2, the piperidine ring adopts a twist-boat conformation. The phenyl rings substituted at the 2- and 6-positions of the piperidine ring subtend dihedral angles of 60.6 (2) and 84.2 (1)°, respectively, with the mean plane of the piperidine ring. In the crystal, mol-ecules are linked by C-H⋯O inter-actions into zigzag chains running along the c-axis direction.
متن کامل1-Chloroacetyl-3-isopropyl-r-2,c-6-diphenylpiperidin-4-one
In the title compound, C(22)H(24)ClNO(2), the piperidine ring adopts a distorted boat conformation. The dihedral angle between the two phenyl rings is 83.2 (1)°. In the crystal, the mol-ecules are linked into chains running along the b axis by C-H⋯O hydrogen bonds. The Cl atom of the chloro-acetyl group is disordered over two positions with occupancies of 0.66 (2) and 0.34 (2).
متن کامل2-Isopropyl-6-methylpyrimidin-4(3H)-one
The mol-ecular structure of the title compound, C(8)H(12)N(2)O, indicates that 2-isopropyl-6-methyl-pyrimidin-4-ol (the enol-form) undergoes an enol-to-keto tautomerism during the crystallization process. The pyrimidin-4(3H)-one group is essentially planar, with a maximum deviation of 0.081 (1) Å for the O atom. In the crystal structure, symmetry-related mol-ecules are linked into centrosymmeti...
متن کامل1-Chloroacetyl-r-2,c-6-bis(4-methoxyphenyl)-c-3,t-3-dimethylpiperidin-4-one
In the title compound, C(23)H(26)ClNO(4), the piperidine ring adopts a distorted boat conformation. The two methoxy-phenyl groups at the 2 and 6 positions of the piperidine ring are in axial and equatorial orientations. An intra-molecular C-H⋯Cl inter-action is observed. In the crystal, the mol-ecules are linked into zigzag chains along the b axis by C-H⋯π inter-molecular inter-actions.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s160053680905497x