1-(2-Vinyl-pyridin-3-yl)propanal O-methyloxime and 1-(6-Vinyl-pyridin-3-yl)propanal O-methyloxime
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Poly[aqua{μ3-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ5 N,N′:O 1,O 1′:O 3}cobalt(II)]
In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxyl-ate O atoms from two 5-[(pyridin-2-ylmeth-yl)amino]-isophthalate anions, two N atoms from a (pyridin-2-ylmeth-yl)amino group and an O atom from a water mol-ecule, furnishing a distorted CoO(4)N(2) octa-hedral geometry. Each anion acts as a μ(3)-bridge, linking cobalt ions into a ...
متن کاملBis[3-dimethylamino-1-(pyridin-2-yl)prop-2-en-1-one-κ2 N 1,O]tris(nitrato-κ2 O,O)gadolinium(III) ethanol disolvate
In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one) ligands and six O atoms from three nitrate anions in a distorted bicapped square-anti-prismatic geometry. In the cr...
متن کامل[2,6-Difluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC 4](pentane-2,4-dionato-κ2 O,O′)iridium(III)
The title compound, [Ir(C10H5F2N2)2(C5H7O2)], has a distorted octa-hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-di-fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)°]. The mol-ecular structure is stabilized by weak C-H⋯O and C-H⋯F hydrogen-bond inter-actions....
متن کاملDi-μ-adipato-κ4 O 1:O 6-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ2 N 2,N 3]copper(II)}
In the centrosymmetric binuclear title complex, [Cu₂(C₆H₈O₄)₂(C₂₀H₁₄N₄)₂(H₂O)₂] or [Cu₂(PDPT)₂(C₆H₈O₄)₂(H₂O)₂] (PDPT = 3-(2-pyrid-yl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two PDPT N atoms and two O atoms from different adipate dianions while a water mol-ecule is located at the apical position. Of...
متن کامل6-[6-(Pyridin-2-yl)-1,2,4,5-tetra-zin-3-yl]pyridin-3-amine monohydrate.
The packing of the title compound, C12H9N7·H2O, is dominated by hydrogen bonding and π-stacking. Layers parallel to [010] are established by hydrogen bonds involving all amine donor functions and one of the water donor functions, while the remaining water donor function enables the stacking of the layers along [10-1], which is accompanied by π-stacking. In the molecule, the plane of the central...
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ژورنال
عنوان ژورنال: Molecules
سال: 2001
ISSN: 1420-3049
DOI: 10.3390/m201