منابع مشابه
β-d-Gulose
The title compound, C6H12O6, a C-3 position epimer of d-galactose, crystallized from an aqueous solution, was confirmed as β-d-pyran-ose with a (4) C 1 (C1) conformation. In the crystal, O-H⋯O hydrogen bonds between the hy-droxy groups at the C-1 and C-6 positions connect mol-ecules into a tape structure with an R 3 (3)(11) ring motif running along the a-axis direction. The tapes are connected ...
متن کاملGulose as a constituent of a
The extracellular matrix (ECM) of the multicellular green alga VOIW.Y carieri contains insoluble fibrous layers that surround individual cells to form contiguous cellular compartments. A highly sulphated glycoprotein with an apparent molecular mass of 185 kDa (SSG I SS) has been identified as the monomeric precursor of this distinct substructure within the ECM [1,2]. The polypeptide chain of SS...
متن کاملβ-d-Altrose
The mol-ecule of the title compound, C(6)H(12)O(6), [systematic name: (2R,3S,4R,5R,6R)-6-(hydroxy-meth-yl)oxane-2,3,4,5-tetrol] adopts a (4)C(1) chair conformation with the anomeric hydroxyl group in the equatorial position. All hydroxyl groups act as donors and acceptors in hydrogen bonding and the mol-ecule is involved in ten inter-molecular O-H⋯O inter-actions [O⋯O = 2.672 (5)-2.776 (4) Å] w...
متن کاملStereoselective protecting group free synthesis of D,L-gulose ethyl glycoside via multicomponent enyne cross metathesis--hetero Diels-Alder reaction.
An efficient and stereoselective synthesis of D,L-gulose was described. The key step of the synthetic route is represented by a multicomponent enyne cross metathesis-hetero Diels-Alder reaction which allows the formation of the pyran ring from cheap and commercially available substrates in a single synthetic step. The synthesis of D,L-gulose was accomplished without the use of protecting groups...
متن کاملAcquired Class D β-Lactamases.
The Class D β-lactamases have emerged as a prominent resistance mechanism against β-lactam antibiotics that previously had efficacy against infections caused by pathogenic bacteria, especially by Acinetobacter baumannii and the Enterobacteriaceae. The phenotypic and structural characteristics of these enzymes correlate to activities that are classified either as a narrow spectrum, an extended s...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2014
ISSN: 1600-5368
DOI: 10.1107/s1600536814008046