oxidative addition reactions of 1,4-diiodo-butane and 1,3-diiodo-propane with [ptme2(ph2phen)]; in which ph2phen=4,7-diphenyl-1,10-phenanthroline, were studied in different solvents such as acetone and benzene.oxidative addition reaction of [pt me2(ph2phen)] with i(ch2)4i and i(ch2)3i produced the [pt me2i(ch2)4(ph2phen)i] (1a) and [pt me2i(ch2)3(ph2phen)i] (1b).all the platinum (iv) products were characterized by 1h-nmr and 13c-nmr spectroscopy and elemental analysis